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Nature's hydrides: rapid reduction of halocarbons by folate model compounds
Halocarbons R–X are reduced to hydrocarbons R–H by folate model compounds under biomimetic conditions. The reactions correspond to a halide–hydride exchange with the methylenetetrahydrofolate (MTHF) models acting as hydride donors. The MTHF models are also functional equivalents of dehalohydrogenase...
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Izdano u: | Chem Sci |
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Glavni autori: | , , , , |
Format: | Artigo |
Jezik: | Inglês |
Izdano: |
Royal Society of Chemistry
2017
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Teme: | |
Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5424806/ https://ncbi.nlm.nih.gov/pubmed/28553478 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc04314c |
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