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Synthesis of Chiral Tetrahydrofurans and Pyrrolidines by Visible‐Light‐Mediated Deoxygenation

The synthesis of chiral tetrahydrofurans and pyrrolidines starting from 1,2‐diols or β‐amino alcohols, respectively, by visible‐light‐mediated deoxygenation is described. Easily accessible monoallylated/propargylated substrates were activated either as inexpensive ethyl oxalates or as recyclable 3,5...

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Detalhes bibliográficos
Publicado no:European J Org Chem
Main Authors: Rackl, Daniel, Kais, Viktor, Lutsker, Eugen, Reiser, and Oliver
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5412674/
https://ncbi.nlm.nih.gov/pubmed/28529446
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.201700014
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