[Ag(115)S(34)(SCH(2)C(6)H(4) (t)Bu)(47)(dpph)(6)]: synthesis, crystal structure and NMR investigations of a soluble silver chalcogenide nanocluster

With the aim to synthesize soluble cluster molecules, the silver salt of (4-(tert-butyl)phenyl)methanethiol [AgSCH(2)C(6)H(4) (t)Bu] was applied as a suitable precursor for the formation of a nanoscale silver sulfide cluster. In the presence of 1,6-(diphenylphosphino)hexane (dpph), the 115 nuclear s...

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Bibliografische gegevens
Gepubliceerd in:Chem Sci
Hoofdauteurs: Bestgen, Sebastian, Fuhr, Olaf, Breitung, Ben, Kiran Chakravadhanula, Venkata Sei, Guthausen, Gisela, Hennrich, Frank, Yu, Wen, Kappes, Manfred M., Roesky, Peter W., Fenske, Dieter
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: Royal Society of Chemistry 2017
Onderwerpen:
Chemistry
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5408567/
https://ncbi.nlm.nih.gov/pubmed/28507679
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc04578b
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