Second-Order Biomimicry: In Situ Oxidative Self-Processing Converts Copper(I)/Diamine Precursor into a Highly Active Aerobic Oxidation Catalyst

[Image: see text] A homogeneous Cu-based catalyst system consisting of [Cu(MeCN)(4)]PF(6), N,N′-di-tert-butylethylenediamine (DBED), and p-(N,N-dimethylamino)pyridine (DMAP) mediates efficient aerobic oxidation of alcohols. Mechanistic study of this reaction shows that the catalyst undergoes an in s...

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Bibliographic Details
Published in:ACS Cent Sci
Main Authors: McCann, Scott D., Lumb, Jean-Philip, Arndtsen, Bruce A., Stahl, Shannon S.
Format: Artigo
Language:Inglês
Published: American Chemical Society 2017
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5408333/
https://ncbi.nlm.nih.gov/pubmed/28470049
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscentsci.7b00022
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