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Second-Order Biomimicry: In Situ Oxidative Self-Processing Converts Copper(I)/Diamine Precursor into a Highly Active Aerobic Oxidation Catalyst
[Image: see text] A homogeneous Cu-based catalyst system consisting of [Cu(MeCN)(4)]PF(6), N,N′-di-tert-butylethylenediamine (DBED), and p-(N,N-dimethylamino)pyridine (DMAP) mediates efficient aerobic oxidation of alcohols. Mechanistic study of this reaction shows that the catalyst undergoes an in s...
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| Publicado no: | ACS Cent Sci |
|---|---|
| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical Society
2017
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5408333/ https://ncbi.nlm.nih.gov/pubmed/28470049 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscentsci.7b00022 |
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