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CO/O(2) assisted oxidative carbon–carbon and carbon–heteroatom bond cleavage for the synthesis of oxosulfonates from DMSO and olefins

Selective carbon–carbon and carbon–heteroatom bond cleavage was achieved in a one reaction system. With this strategy a novel Pd/Cu-catalyzed aerobic oxidative oxosulfonation of olefins with DMSO has been developed. Preliminary mechanistic investigations indicated that CO/O(2) assisted the bond clea...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Shao, Ailong, Gao, Meng, Chen, Songtao, Wang, Tao, Lei, Aiwen
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5407263/
https://ncbi.nlm.nih.gov/pubmed/28507671
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc04480h
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