Physicochemical and Electronic Properties of Cationic [6]Helicenes, from Chemical and Electrochemical Stabilities to Far-Red (Polarized) Luminescence

Physicochemical properties of cationic dioxa 1, azaoxa 2 and diaza 3 [6]helicenes demonstrate a much higher chemical stability of diaza adduct 3 (pK(R+) 20.4, [Formula: see text] −0.72 V) compared to azaoxa 2 (pK(R+) 15.2, [Formula: see text] −0.45 V) and dioxa 1 (pK(R+) 8.8, [Formula: see text] −0....

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Publicado no:Chemistry
Main Authors: Bosson, Johann, Labrador, Geraldine M., Pascal, Simon, Miannay, François-Alexandre, Yushchenko, Oleksandr, Li, Haidong, Bouffier, Laurent, Sojic, Neso, Tovar, Roberto C., Muller, Gilles, Jacquemin, Denis, Laurent, Adèle D., Le Guennic, Boris, Vauthey, Eric, Lacour, Jérôme
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5396952/
https://ncbi.nlm.nih.gov/pubmed/27885721
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201603591
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