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Electron Solvation and the Unique Liquid Structure of a Mixed‐Amine Expanded Metal: The Saturated Li–NH(3)–MeNH(2) System

Metal–amine solutions provide a unique arena in which to study electrons in solution, and to tune the electron density from the extremes of electrolytic through to true metallic behavior. The existence and structure of a new class of concentrated metal‐amine liquid, Li–NH(3)–MeNH(2), is presented in...

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Veröffentlicht in:Angew Chem Int Ed Engl
Hauptverfasser: Seel, Andrew G., Swan, Helen, Bowron, Daniel T., Wasse, Jonathan C., Weller, Thomas, Edwards, Peter P., Howard, Christopher A., Skipper, Neal T.
Format: Artigo
Sprache:Inglês
Veröffentlicht: John Wiley and Sons Inc. 2017
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5396365/
https://ncbi.nlm.nih.gov/pubmed/28071838
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201609192
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