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N‐Methyl‐Benzothiazolium Salts as Carbon Lewis Acids for Si−H σ‐Bond Activation and Catalytic (De)hydrosilylation
N−Me‐Benzothiazolium salts are introduced as a new family of Lewis acids able to activate Si−H σ bonds. These carbon‐centred Lewis acids were demonstrated to have comparable Lewis acidity towards hydride as found for the triarylboranes widely used in Si−H σ‐bond activation. However, they display low...
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| Publicado no: | Chemistry |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5396135/ https://ncbi.nlm.nih.gov/pubmed/27780294 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201604613 |
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