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Selective Hydrogenation of Nitriles to Primary Amines Catalyzed by a Polysilane/SiO(2)‐Supported Palladium Catalyst under Continuous‐Flow Conditions

Hydrogenation of nitriles to primary amines with heterogeneous catalysts under liquid‐phase continuous‐flow conditions is described. Newly developed polysilane/SiO(2)‐supported Pd was found to be an effective catalyst and various nitriles were converted into primary amine salts in almost quantitativ...

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Detalhes bibliográficos
Publicado no:ChemistryOpen
Main Authors: Saito, Yuki, Ishitani, Haruro, Ueno, Masaharu, Kobayashi, Shū
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5390790/
https://ncbi.nlm.nih.gov/pubmed/28413753
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.201600166
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