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Anisotropic Charge Distribution and Anisotropic van der Waals Radius Leading to Intriguing Anisotropic Noncovalent Interactions

Although group (IV–VII) nonmetallic elements do not favor interacting with anionic species, there are counterexamples including the halogen bond. Such binding is known to be related to the charge deficiency because of the adjacent atom's electron withdrawing effect, which creates σ/π-holes at t...

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Detalhes bibliográficos
Publicado no:Sci Rep
Main Authors: Kim, Hahn, Van Dung Doan, Cho, Woo Jong, Madhav, Miriyala Vijay, Kim, Kwang S.
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group 2014
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5376054/
https://ncbi.nlm.nih.gov/pubmed/25059645
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep05826
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