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Pairwise hydrogen addition in the selective semihydrogenation of alkynes on silica-supported Cu catalysts
Mechanistic insight into the semihydrogenation of 1-butyne and 2-butyne on Cu nanoparticles supported on partially dehydroxylated silica (Cu/SiO(2-700)) was obtained using parahydrogen. Hydrogenation of 1-butyne over Cu/SiO(2-700) yielded 1-butene with ≥97% selectivity. The surface modification of t...
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| Udgivet i: | Chem Sci |
|---|---|
| Main Authors: | , , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Royal Society of Chemistry
2017
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5369404/ https://ncbi.nlm.nih.gov/pubmed/28451349 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc05276b |
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