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Zirconocene catalyzed diastereoselective carbometalation of cyclobutenes

The regio- and diastereoselective zirconocene-catalyzed carbomagnesiation of cyclobutenes is herein reported to afford configurationally stable cyclobutylmagnesium species that could subsequently react with a large variety of electrophiles to give polysubstituted cyclobutane species as a single dias...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Roy, Sudipta Raha, Eijsberg, Hendrik, Bruffaerts, Jeffrey, Marek, Ilan
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5365058/
https://ncbi.nlm.nih.gov/pubmed/28451177
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc02617f
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