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Computational and Experimental Evidence of Emergent Equilibrium Isotope Effects in Anion Receptor Complexes
[Image: see text] The measurement of a deuterium equilibrium isotope effect (EIE) for the aryl CH···Cl(–) interaction of anion receptor 1H/1D is reported. Computations corroborate the results of solution measurements for a small, normal EIE in the full complex (K(a)(H)/K(a)(D) = 1.019 ± 0.010). Inte...
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| Publicado no: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical
Society
2017
|
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5364433/ https://ncbi.nlm.nih.gov/pubmed/28282134 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b00612 |
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