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Fluorinated antimony(v) derivatives: strong Lewis acidic properties and application to the complexation of formaldehyde in aqueous solutions

As part of our ongoing studies of water tolerant Lewis acids, we have synthesized and investigated the properties of Sb(C(6)F(5))(3)(O(2)C(6)Cl(4)), a fluorinated stiborane whose Lewis acidity approaches that of B(C(6)F(5))(3). While chloroform solutions of this Lewis acid can be kept open to air or...

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Pubblicato in:Chem Sci
Autori principali: Tofan, Daniel, Gabbaï, François P.
Natura: Artigo
Lingua:Inglês
Pubblicazione: Royal Society of Chemistry 2016
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5363782/
https://ncbi.nlm.nih.gov/pubmed/28451122
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc02558g
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