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Fluorinated antimony(v) derivatives: strong Lewis acidic properties and application to the complexation of formaldehyde in aqueous solutions

As part of our ongoing studies of water tolerant Lewis acids, we have synthesized and investigated the properties of Sb(C(6)F(5))(3)(O(2)C(6)Cl(4)), a fluorinated stiborane whose Lewis acidity approaches that of B(C(6)F(5))(3). While chloroform solutions of this Lewis acid can be kept open to air or...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Tofan, Daniel, Gabbaï, François P.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5363782/
https://ncbi.nlm.nih.gov/pubmed/28451122
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc02558g
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