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Dynamics and the Regiochemistry of Nitration of Toluene

The regiochemistry of the nitration of toluene by NO(2)(+)BF(4)(−) in dichloromethane is accurately predicted from trajectories in explicit solvent. Simpler models and approaches based on transition state theory fail to account for the selectivity. Potential of mean force calculations find no free-e...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Nieves-Quinones, Yexenia, Singleton, Daniel A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5358517/
https://ncbi.nlm.nih.gov/pubmed/27794598
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b07328
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