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6-exo-trig Michael addition-lactonizations for catalytic enantioselective chromenone synthesis
The catalytic enantioselective 6-exo-trig Michael addition-lactonization of enone-acid substrates to form cis-chromenones with high diastereo- and enantiocontrol was developed using the commercially available isothiourea tetramisole. An acidic workup proved necessary to minimize product epimerizatio...
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| Publicado no: | Chem Commun (Camb) |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5358503/ https://ncbi.nlm.nih.gov/pubmed/28133660 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6cc10178j |
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