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Nanorings with copper(ii) and zinc(ii) centers: forcing copper porphyrins to bind axial ligands in heterometallated oligomers

The affinity of copper(ii) porphyrins for pyridine ligands is extremely weak, but oligo-pyridine templates can be used to direct the synthesis of Cu-containing cyclic porphyrin oligomers when they also have Zn centers. We report the synthesis of two heterometallated nanorings: a six-porphyrin ring p...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Cremers, Jonathan, Richert, Sabine, Kondratuk, Dmitry V., Claridge, Tim D. W., Timmel, Christiane R., Anderson, Harry L.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5355962/
https://ncbi.nlm.nih.gov/pubmed/28451130
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc01809b
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