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Distortion dependent intersystem crossing: A femtosecond time-resolved photoelectron spectroscopy study of benzene, toluene, and p-xylene

The competition between ultrafast intersystem crossing and internal conversion in benzene, toluene, and p-xylene is investigated with time-resolved photoelectron spectroscopy and quantum chemical calculations. By exciting to S(2) out-of-plane symmetry breaking, distortions are activated at early tim...

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Библиографические подробности
Опубликовано в: :Struct Dyn
Главные авторы: Stephansen, Anne B., Sølling, Theis I.
Формат: Artigo
Язык:Inglês
Опубликовано: American Crystallographic Association 2017
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC5336472/
https://ncbi.nlm.nih.gov/pubmed/28345010
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4977735
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