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Manganese(II) catalyzes the bicarbonate-dependent oxidation of amino acids by hydrogen peroxide and the amino acid-facilitated dismutation of hydrogen peroxide.

In bicarbonate/CO2 buffer, Mn(II) and Fe(II) catalyze the oxidation of amino acids by H2O2 and the dismutation of H2O2. As the Mn(II)/Fe(II) ratio is increased, the yield of carbonyl compounds per mole of leucine oxidized is essentially constant, but the ratio of alpha-ketoisocaproate to isovalerald...

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Pubblicato in:Proc Natl Acad Sci U S A
Autori principali: Berlett, B S, Chock, P B, Yim, M B, Stadtman, E R
Natura: Artigo
Lingua:Inglês
Pubblicazione: National Academy of Sciences 1990
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Accesso online:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC53269/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/2296594/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.87.1.389
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