Nacnac‐Cobalt‐Mediated P(4) Transformations

A comparison of P(4) activations mediated by low‐valent β‐diketiminato (L) cobalt complexes is presented. The formal Co(0) source [K(2)(L(3)Co)(2)(μ(2):η(1),η(1)‐N(2))] (1) reacts with P(4) to form a mixture of the monoanionic complexes [K(thf)(6)][(L(3)Co)(2)(μ(2):η(4),η(4)‐P(4))] (2) and [K(thf)(6...

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發表在:Chemistry
Main Authors: Spitzer, Fabian, Graßl, Christian, Balázs, Gábor, Mädl, Eric, Keilwerth, Martin, Zolnhofer, Eva M., Meyer, Karsten, Scheer, Manfred
格式: Artigo
語言:Inglês
出版: John Wiley and Sons Inc. 2017
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC5324690/
https://ncbi.nlm.nih.gov/pubmed/28032678
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201605451
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