Ultralarge 3d/4f Coordination Wheels: From Carboxylate/Amino Alcohol-Supported {Fe(4)Ln(2)} to {Fe(18)Ln(6)} Rings

[Image: see text] A family of wheel-shaped charge-neutral heterometallic {Fe(III)(4)Ln(III)(2)}- and {Fe(III)(18)M(III)(6)}-type coordination clusters demonstrates the intricate interplay of solvent effects and structure-directing roles of semiflexible bridging ligands. The {Fe(4)Ln(2)}-type compoun...

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Udgivet i:Inorg Chem
Main Authors: Botezat, Olga, van Leusen, Jan, Kravtsov, Victor Ch., Kögerler, Paul, Baca, Svetlana G.
Format: Artigo
Sprog:Inglês
Udgivet: American Chemical Society 2017
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5320538/
https://ncbi.nlm.nih.gov/pubmed/28135085
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.6b02100
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