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Atom tunnelling in the reaction NH(3) (+) + H(2) → NH(4) (+) + H and its astrochemical relevance

The title reaction is involved in the formation of ammonia in the interstellar medium. We have calculated thermal rates including atom tunnelling using different rate theories. Canonical variational theory with microcanonically optimised multidimensional tunnelling was used for bimolecular rates, mo...

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Detalhes bibliográficos
Publicado no:Faraday Discuss
Main Authors: Álvarez-Barcia, Sonia, Russ, Marie-Sophie, Meisner, Jan, Kästner, Johannes
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5317219/
https://ncbi.nlm.nih.gov/pubmed/27711847
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6fd00096g
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