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The Cobalt cyclo‐P(4) Sandwich Complex and Its Role in the Formation of Polyphosphorus Compounds

A synthetic approach to the sandwich complex [Cp′′′Co(η(4)‐P(4))] (2) containing a cyclo‐P(4) ligand as an end‐deck was developed. Complex 2 is the missing homologue in the series of first‐row cyclo‐P(n) sandwich complexes, and shows a unique tendency to dimerize in solution to form two isomeric P(8...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Dielmann, Fabian, Timoshkin, Alexey, Piesch, Martin, Balázs, Gábor, Scheer, Manfred
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5299486/
https://ncbi.nlm.nih.gov/pubmed/28078794
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201610967
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