Four-step iron(ii) spin state cascade driven by antagonistic solid state interactions

A four-stepped cascade of Fe(ii) high spin (HS) to low spin (LS) states is demonstrated in a family of 2-D Hofmann materials, [Fe(3) (II)(saltrz)(6)(M(II)(CN)(4))(3)]·8(H(2)O) (M(II) = Pd (1(Pd) ), Pt (1(Pt) ); saltrz = (E)-2-(((4H-1,2,4-triazol-4-yl)imino)methyl)phenol). Alongside the fully HS and...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Sciortino, Natasha F., Zenere, Katrina A., Corrigan, Maggie E., Halder, Gregory J., Chastanet, Guillaume, Létard, Jean-François, Kepert, Cameron J., Neville, Suzanne M.
Format: Artigo
Language:Inglês
Published: Royal Society of Chemistry 2017
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5297924/
https://ncbi.nlm.nih.gov/pubmed/28451220
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc03114e
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