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Reassignment of the absolute configuration of plakinidone from the sponge consortium Plakortis halichondrioides–Xestospongia deweerdtae using a combination of synthesis and a chiroptical approach

Recent work by Wu et al. in connection with the first synthesis of the marine natural product plakinidone revealed that the most salient feature of its purported structure, a six-membered perlactone moiety, was in fact a five-membered lactone, i.e. a 3-methyl-4-hydroxy-2(5H)-furanone or tetronic aci...

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Foilsithe in:Tetrahedron Asymmetry
Main Authors: Jiménez-Romero, Carlos, Rode, Joanna E., Rodríguez, Abimael D.
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2016
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5295471/
https://ncbi.nlm.nih.gov/pubmed/28190935
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetasy.2016.03.011
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