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Synergistic Photoredox/Nickel Coupling of Acyl Chlorides with Secondary Alkyltrifluoroborates: Dialkyl Ketone Synthesis

[Image: see text] Visible light photoredox/nickel dual catalysis has been employed in the cross-coupling of acyl chlorides with potassium alkyltrifluoroborates. This protocol, based on single-electron-mediated alkyl transfer, circumvents the restriction of using reactive alkylmetallic nucleophiles i...

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書目詳細資料
發表在:J Org Chem
Main Authors: Amani, Javad, Molander, Gary A.
格式: Artigo
語言:Inglês
出版: American Chemical Society 2017
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC5295362/
https://ncbi.nlm.nih.gov/pubmed/28093913
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.6b02897
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