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Indefinitely stable iron(IV) cage complexes formed in water by air oxidation

In nature, iron, the fourth most abundant element of the Earth's crust, occurs in its stable forms either as the native metal or in its compounds in the +2 or +3 (low-valent) oxidation states. High-valent iron (+4, +5, +6) compounds are not formed spontaneously at ambient conditions, and the on...

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Publicado en:Nat Commun
Autores principales: Tomyn, Stefania, Shylin, Sergii I., Bykov, Dmytro, Ksenofontov, Vadim, Gumienna-Kontecka, Elzbieta, Bon, Volodymyr, Fritsky, Igor O.
Formato: Artigo
Lenguaje:Inglês
Publicado: Nature Publishing Group 2017
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC5253674/
https://ncbi.nlm.nih.gov/pubmed/28102364
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms14099
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