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Stereocontrolled Syntheses of Seven-membered Carbocycles via Tandem Allene Aziridination/[4 + 3] Reaction

A tandem allene aziridination/[4+3]/reduction sequence converts simple homoallenic sulfamates to densely functionalized aminated cycloheptenes, where the relative stereochemistry at five contiguous asymmetric centers can be controlled through the choice of the solvent and the reductant. The products...

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Bibliografiska uppgifter
I publikationen:Angew Chem Int Ed Engl
Huvudupphovsmän: Gerstner, Nels C., Adams, Christopher S., Tretbar, Maik, Schomaker, Jennifer M.
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2016
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC5218842/
https://ncbi.nlm.nih.gov/pubmed/27709816
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201606195
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