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Stereocontrolled Syntheses of Seven-membered Carbocycles via Tandem Allene Aziridination/[4 + 3] Reaction
A tandem allene aziridination/[4+3]/reduction sequence converts simple homoallenic sulfamates to densely functionalized aminated cycloheptenes, where the relative stereochemistry at five contiguous asymmetric centers can be controlled through the choice of the solvent and the reductant. The products...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5218842/ https://ncbi.nlm.nih.gov/pubmed/27709816 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201606195 |
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