Luminescent Gold(III) Thiolates: Supramolecular Interactions Trigger and Control Switchable Photoemissions from Bimolecular Excited States

A new family of cyclometallated gold(III) thiolato complexes based on pyrazine‐centred pincer ligands has been prepared, (C^N(pz)^C)AuSR, where C^N(pz)^C=2,6‐bis(4‐Bu(t)C(6)H(4))pyrazine dianion and R=Ph (1), C(6)H(4) tBu‐4 (2), 2‐pyridyl (3), 1‐naphthyl (1‐Np, 4), 2‐Np (5), quinolinyl (Quin, 6), 4‐...

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Publicat a:Chemistry
Autors principals: Currie, Lucy, Fernandez‐Cestau, Julio, Rocchigiani, Luca, Bertrand, Benoît, Lancaster, Simon J., Hughes, David L., Duckworth, Helen, Jones, Saul T. E., Credgington, Dan, Penfold, Thomas J., Bochmann, Manfred
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2016
Matèries:
Full Papers
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5215685/
https://ncbi.nlm.nih.gov/pubmed/27859790
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201603841
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