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Crystal structure of μ-carbonyl-1:2κ(2) C:C-carbonyl-1κC-(1η(5)-cyclopentadienyl)iodido-2κI-[μ-2-(pyridin-2-yl)ethene-1,1-diyl-1κC (1):2κ(2) N,C (1)]ironpalladium(Fe—Pd) benzene monosolvate
The reaction of Cp(CO)(2)FeI with 2-ethynylpyridine under Sonogashira conditions [5% PdCl(2)(PPh(3))(2), 10% CuI, THF–NEt(3) (2:1)] afforded the title binuclear μ-pyridylvinylidene FePd complex (FePd1) as a benzene solvate, [FePd(C(5)H(5))(C(7)H(5)N)I(CO)(2)]·C(6)H(6), in a very low yield rather...
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Publicado no: | Acta Crystallogr E Crystallogr Commun |
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Main Authors: | , , , , , , |
Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
International Union of Crystallography
2017
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5209775/ https://ncbi.nlm.nih.gov/pubmed/28083139 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989016019915 |
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