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Conformation-driven quantum interference effects mediated by through-space conjugation in self-assembled monolayers

Tunnelling currents through tunnelling junctions comprising molecules with cross-conjugation are markedly lower than for their linearly conjugated analogues. This effect has been shown experimentally and theoretically to arise from destructive quantum interference, which is understood to be an intri...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Carlotti, Marco, Kovalchuk, Andrii, Wächter, Tobias, Qiu, Xinkai, Zharnikov, Michael, Chiechi, Ryan C.
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5187444/
https://ncbi.nlm.nih.gov/pubmed/27996036
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms13904
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