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Crystal Fluidity Reflected by Fast Rotational Motion at the Core, Branches and Peripheral Aromatic Groups of a Dendrimeric Molecular Rotor
Low packing densities are key structural features of amphidynamic crystals built with static and mobile components. Here we report a loosely packed crystal of dendrimeric rotor, 2, and the fast dynamics of all its aromatic groups, both resulting from the hyperbranched structure of the molecule. Comp...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5155508/ https://ncbi.nlm.nih.gov/pubmed/26973017 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b01398 |
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