Tying a Molecular Overhand Knot of Single Handedness and Asymmetric Catalysis with the Corresponding Pseudo-D(3)-Symmetric Trefoil Knot

[Image: see text] We report the stereoselective synthesis of a left-handed trefoil knot from a tris(2,6-pyridinedicarboxamide) oligomer with six chiral centers using a lanthanide(III) ion template. The oligomer folds around the lanthanide ion to form an overhand knot complex of single handedness. Su...

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Argitaratua izan da:J Am Chem Soc
Egile Nagusiak: Gil-Ramírez, Guzmán, Hoekman, Steven, Kitching, Matthew O., Leigh, David A., Vitorica-Yrezabal, Iñigo J., Zhang, Gen
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: American Chemical Society 2016
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC5152939/
https://ncbi.nlm.nih.gov/pubmed/27667319
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b08421
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