Amides Do Not Always Work: Observation of Guest Binding in an Amide-Functionalized Porous Metal–Organic Framework

[Image: see text] An amide-functionalized metal organic framework (MOF) material, MFM-136, shows a high CO(2) uptake of 12.6 mmol g(–1) at 20 bar and 298 K. MFM-136 is the first example of an acylamide pyrimidyl isophthalate MOF without open metal sites and, thus, provides a unique platform to study...

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Bibliographic Details
Published in:J Am Chem Soc
Main Authors: Benson, Oguarabau, da Silva, Ivan, Argent, Stephen P., Cabot, Rafel, Savage, Mathew, Godfrey, Harry G.W., Yan, Yong, Parker, Stewart F., Manuel, Pascal, Lennox, Matthew J., Mitra, Tamoghna, Easun, Timothy L., Lewis, William, Blake, Alexander J., Besley, Elena, Yang, Sihai, Schröder, Martin
Format: Artigo
Language:Inglês
Published: American Chemical Society 2016
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5152937/
https://ncbi.nlm.nih.gov/pubmed/27665845
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b08059
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