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Catalysis-based enantioselective total synthesis of the macrocyclic spermidine alkaloid isooncinotine
A concise and efficient total synthesis of the spermidine alkaloid (-)-isooncinotine (1) incorporating a 22-membered lactam ring is outlined. The approach is largely catalysis-based, involving a selective iron-catalyzed alkyl–aryl cross-coupling reaction of a difunctionalized pyridine substrate, a h...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2004
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC514416/ https://ncbi.nlm.nih.gov/pubmed/15141085 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0401322101 |
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