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Overcoming the Crystallization Bottleneck: A Family of Gigantic Inorganic {Pd(x)}(L) (x=84, 72) Palladium Macrocycles Discovered using Solution Techniques

The {Pd(84)}(Ac) wheel, initially discovered serendipitously, is the only reported giant palladium macrocycle—a unique structure that spontaneously assembles from small building blocks. Analogues of this structure are elusive. A new modular route to {Pd(84)}(Ac) is described, allowing incorporation...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Christie, Lorna G., Surman, Andrew J., Scullion, Rachel A., Xu, Feng, Long, De‐Liang, Cronin, Leroy
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5113701/
https://ncbi.nlm.nih.gov/pubmed/27634480
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201606005
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