Ground‐State Chemical Reactivity under Vibrational Coupling to the Vacuum Electromagnetic Field

The ground‐state deprotection of a simple alkynylsilane is studied under vibrational strong coupling to the zero‐point fluctuations, or vacuum electromagnetic field, of a resonant IR microfluidic cavity. The reaction rate decreased by a factor of up to 5.5 when the Si−C vibrational stretching modes...

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Dettagli Bibliografici
Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Thomas, Anoop, George, Jino, Shalabney, Atef, Dryzhakov, Marian, Varma, Sreejith J., Moran, Joseph, Chervy, Thibault, Zhong, Xiaolan, Devaux, Eloïse, Genet, Cyriaque, Hutchison, James A., Ebbesen, Thomas W.
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2016
Soggetti:
Communications
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5113700/
https://ncbi.nlm.nih.gov/pubmed/27529831
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201605504
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