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Crystal structures of di-μ-bromido-bis{dibromido[η(5)-2-(dimethylamino)indenyl]zirconium(IV)} and dibromidobis[η(5)-2-(dimethylamino)indenyl]zirconium(IV)

In the title compounds, [Zr(2)Br(6)(C(11)H(12)N)(2)], (I) and [ZrBr(2)(C(11)H(12)N)(2)], (II), the positions of the η(5)-binding 2-dimethylaminoindenyl units are fixed by intramolecular C—H⋯Br interactions involving aromatic or dimethylamino H atoms. The binuclear molecule of (I) is located...

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Detalhes bibliográficos
Publicado no:	Acta Crystallogr E Crystallogr Commun
Main Authors:	Medvedev, Michael G., Borisov, Ilya S., Kulyabin, Pavel S., Izmer, Vyatcheslav V., Kononovich, Dmitry S., Uborsky, Dmitry V., Voskoboynikov, Alexander Z.
Formato:	Artigo
Idioma:	Inglês
Publicado em:	International Union of Crystallography 2016
Assuntos:	Research Communications
Acesso em linha:	https://ncbi.nlm.nih.gov/pmc/articles/PMC5095842/ https://ncbi.nlm.nih.gov/pubmed/27840717 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989016016595
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Crystal structures of di-μ-bromido-bis{di­bromido­[η(5)-2-(di­methyl­amino)­inden­yl]zirconium(IV)} and di­bromido­bis­[η(5)-2-(di­methyl­amino)­inden­yl]zirconium(IV)

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Crystal structures of di-μ-bromido-bis{dibromido[η(5)-2-(dimethylamino)indenyl]zirconium(IV)} and dibromidobis[η(5)-2-(dimethylamino)indenyl]zirconium(IV)