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A DFT Study of CO(2) Hydrogenation on Faujasite‐Supported Ir(4) Clusters: on the Role of Water for Selectivity Control

Reaction mechanisms for the catalytic hydrogenation of CO(2) by faujasite‐supported Ir(4) clusters were studied by periodic DFT calculations. The reaction can proceed through two alternative paths. The thermodynamically favoured path results in the reduction of CO(2) to CO, whereas the other, kineti...

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Bibliografiske detaljer
Udgivet i:ChemCatChem
Main Authors: Szyja, Bartłomiej M., Smykowski, Daniel, Szczygieł, Jerzy, Hensen, Emiel J. M., Pidko, Evgeny A.
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2016
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5094556/
https://ncbi.nlm.nih.gov/pubmed/27840663
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cctc.201600644
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