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Pressure-Driven Spin Crossover Involving Polyhedral Transformation in Layered Perovskite Cobalt Oxyfluoride
We report a novel pressure-driven spin crossover in layered cobalt oxyfluoride Sr(2)CoO(3)F with a distorted CoO(5) square pyramid loosely bound with a fluoride ion. Upon increasing pressure, the spin state of the Co(III) cation gradually changes from a high spin state (S = 2) to a low spin state (S...
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| Publicado no: | Sci Rep |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Nature Publishing Group
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5090247/ https://ncbi.nlm.nih.gov/pubmed/27805031 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep36253 |
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