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n→π* Interactions are Competitive with Hydrogen Bonds
Because carbonyl groups can participate in both hydrogen bonds and n→π* interactions, these two interactions likely affect one another. Herein, enhancement of an amidic n→π* interaction is shown to reduce the ability of β-keto amides to tautomerize to the enol, indicating decreased hydrogen-bonding...
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| Publicado no: | Org Lett |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5089869/ https://ncbi.nlm.nih.gov/pubmed/27409515 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b01655 |
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