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Mechanism of O(2) activation and substrate hydroxylation in noncoupled binuclear copper monooxygenases

Peptidylglycine α-hydroxylating monooxygenase (PHM) and dopamine β-monooxygenase (DβM) are copper-dependent enzymes that are vital for neurotransmitter regulation and hormone biosynthesis. These enzymes feature a unique active site consisting of two spatially separated (by 11 Å in PHM) and magnetica...

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Dades bibliogràfiques
Publicat a:Proc Natl Acad Sci U S A
Autors principals: Cowley, Ryan E., Tian, Li, Solomon, Edward I.
Format: Artigo
Idioma:Inglês
Publicat: National Academy of Sciences 2016
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5087064/
https://ncbi.nlm.nih.gov/pubmed/27790986
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1614807113
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