Superelectrophilic activation of 5-hydroxymethylfurfural and 2,5-diformylfuran: organic synthesis based on biomass-derived products

The reaction of 5-hydroxymethylfurfural (5-HMF) with arenes in superacidic trifluoromethanesulfonic acid (triflic acid, TfOH) as the solvent at room temperature for 1–24 h gives rise to 5-arylmethylfurfurals (yields of 17–91%) and 2-arylmethyl-5-(diarylmethyl)furans (yields of 10–37%). The formation...

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Bibliografiske detaljer
Udgivet i:Beilstein J Org Chem
Main Authors: Ryabukhin, Dmitry S, Zakusilo, Dmitry N, Kompanets, Mikhail O, A.Tarakanov, Anton, Boyarskaya, Irina A, Artamonova, Tatiana O, Khohodorkovskiy, Mikhail A, Opeida, Iosyp O, Vasilyev, Aleksander V
Format: Artigo
Sprog:Inglês
Udgivet: Beilstein-Institut 2016
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Full Research Paper
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5082471/
https://ncbi.nlm.nih.gov/pubmed/27829919
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.202
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