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Electrocatalytic and Solar‐Driven CO(2) Reduction to CO with a Molecular Manganese Catalyst Immobilized on Mesoporous TiO(2)
Electrocatalytic CO(2) reduction to CO was achieved with a novel Mn complex, fac‐[MnBr(4,4′‐bis(phosphonic acid)‐2,2′‐bipyridine)(CO)(3)] (MnP), immobilized on a mesoporous TiO(2) electrode. A benchmark turnover number of 112±17 was attained with these TiO(2)|MnP electrodes after 2 h electrolysis. P...
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| Veröffentlicht in: | Angew Chem Int Ed Engl |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
John Wiley and Sons Inc.
2016
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5074277/ https://ncbi.nlm.nih.gov/pubmed/27110904 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201601038 |
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