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Cinchonium Betaines as Efficient Catalysts for Asymmetric Proton Transfer Catalysis: The Development of a Practical Enantioselective Isomerization of Trifluoromethyl Imines
We have developed a new class of cinchonium betaine catalysts bearing both a base moiety and an aromatic moiety as an N-substituent of the quinuclidine motif. These cinchonium betains were found to promote proton transfer catalysis with 1000–5000 turnovers per 24 hours, thereby enabling us to realiz...
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| Pubblicato in: | J Am Chem Soc |
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| Autori principali: | , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2016
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5072400/ https://ncbi.nlm.nih.gov/pubmed/27579574 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b08727 |
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