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α-Hydroxy coordination of mononuclear vanadyl citrate, malate and S-citramalate with N−heterocycle ligand, implying a new protonation pathway of iron-vanadium cofactor in nitrogenase
Unlike the most of α-alkoxy coordination in α-hydroxycarboxylates to vanadium, novel α-hydroxy coordination to vanadium(IV) has been observed for a series of chiral and achiral monomeric α-hydroxycarboxylato vanadyl complexes [VO(H(2)cit)(bpy)]·2H(2)O (1), [VO(Hmal)(bpy)]·H(2)O (2), [VO(H(2)cit)(phe...
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Publicado no: | J Inorg Biochem |
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Main Authors: | , , , , , |
Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
2014
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5065718/ https://ncbi.nlm.nih.gov/pubmed/25240212 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jinorgbio.2014.08.003 |
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