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α-Hydroxy coordination of mononuclear vanadyl citrate, malate and S-citramalate with N−heterocycle ligand, implying a new protonation pathway of iron-vanadium cofactor in nitrogenase

Unlike the most of α-alkoxy coordination in α-hydroxycarboxylates to vanadium, novel α-hydroxy coordination to vanadium(IV) has been observed for a series of chiral and achiral monomeric α-hydroxycarboxylato vanadyl complexes [VO(H(2)cit)(bpy)]·2H(2)O (1), [VO(Hmal)(bpy)]·H(2)O (2), [VO(H(2)cit)(phe...

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Detalhes bibliográficos
Publicado no:J Inorg Biochem
Main Authors: Chen, Can-Yu, Chen, Mao-Long, Chen, Hong-Bin, Wang, Hongxin, Cramer, Stephen P., Zhou, Zhao-Hui
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5065718/
https://ncbi.nlm.nih.gov/pubmed/25240212
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jinorgbio.2014.08.003
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