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Simple phosphinate ligands access zinc clusters identified in the synthesis of zinc oxide nanoparticles

The bottom-up synthesis of ligand-stabilized functional nanoparticles from molecular precursors is widely applied but is difficult to study mechanistically. Here we use (31)P NMR spectroscopy to follow the trajectory of phosphinate ligands during the synthesis of a range of ligated zinc oxo clusters...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Pike, Sebastian D., White, Edward R., Shaffer, Milo S. P., Williams, Charlotte K.
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5065624/
https://ncbi.nlm.nih.gov/pubmed/27734828
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms13008
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