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Enantioselective Cu-Catalyzed Arylation of Secondary Phosphine Oxides with Diaryliodonium Salts toward the Synthesis of P-Chiral Phosphines

[Image: see text] Catalytic synthesis of nonracemic P-chiral phosphine derivatives remains a significant challenge. Here we report Cu-catalyzed enantioselective arylation of secondary phosphine oxides with diaryliodonium salts for the synthesis of tertiary phosphine oxides with high enantiomeric exc...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Beaud, Rodolphe, Phipps, Robert J., Gaunt, Matthew J.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2016
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5065240/
https://ncbi.nlm.nih.gov/pubmed/27689432
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b09334
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