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Asymmetric Synthesis of First Generation Molecular Motors

[Image: see text] A general enantioselective route to functionalized first generation molecular motors is described. An enantioselective protonation of the silyl enol ethers of indanones by a Au(I)BINAP complex sets the stage for a highly diastereoselective McMurry coupling as a second enhancement s...

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: Neubauer, Thomas M., van Leeuwen, Thomas, Zhao, Depeng, Lubbe, Anouk S., Kistemaker, Jos C. M., Feringa, Ben L.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5055213/
https://ncbi.nlm.nih.gov/pubmed/25079823
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol501925f
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